The Solubility of Gases in Liquids 9. Solubility of He, Ne, Ar, Kr, N2, O2, CO, CO2, CH4, CF4, and SF6 in some Dimethylcyclohexanes at 298 to 313 K
The solubility of He, Ne, Ar, Kr, N2, O2, CO, CO2, CH4, CF4, and SF6 in cis-1,2-dimethylcyclohexane, trans-1,2-dimethylcyclohexane, and two binary mixtures of cis-+ trans-1,3-dimethylcyclohexane and cis- + trans-1,4-dimethylcyclohexane, respectively, have been determined at 1 atm pressure in the range 297 to 313 K. From the experimental results, the enthalpy and entropy changes on solution for 1 atm partial pressure of gas and 298.15 K have been calculated. These values have been compared with results obtained through application of scaled-particle theory. Agreement is generally quite satisfactory. On this basis, a recent semi-empirical correlation advanced by Field, Wilhelm, and Battino is tested.
Geller, E. B.,
& Wilhelm, E.
(1976). The Solubility of Gases in Liquids 9. Solubility of He, Ne, Ar, Kr, N2, O2, CO, CO2, CH4, CF4, and SF6 in some Dimethylcyclohexanes at 298 to 313 K. The Journal of Chemical Thermodynamics, 8 (3), 197-202.