The Millimeter-Wave Spectrum of Chlorine Nitrate (ClONO₂): The ν₆ Vibrational State

Authors

Rebecca A. H. Butler
Douglas T. Petkie, Wright State University - Main CampusFollow
Paul Helminger
Frank C. De Lucia
Ewa Bialkowska-Jaworska
Zbigniew Kisiel

Document Type

Article

Publication Date

8-2007

Abstract

The pure rotational spectrum of chlorine nitrate in its v₆ = 1 excited vibrational state has been studied. A total of 2901 lines, with K_a extending to 33 in the ³⁵Cl isotopologue and 30 in the ³⁷Cl isotopologue, respectively, have been recorded and assigned. This analysis, along with our recently reported study of the ν₅/ν₆ν₉ dyad and the improved energy levels of ν₉ reported in this paper, should make possible accurate simulation of the corresponding ν₆ band and its complex hot band structure near 435 cm⁻¹.

Repository Citation

Butler, R. A., Petkie, D. T., Helminger, P., De Lucia, F. C., Bialkowska-Jaworska, E., & Kisiel, Z. (2007). The Millimeter-Wave Spectrum of Chlorine Nitrate (ClONO₂): The ν₆ Vibrational State. Journal of Molecular Spectroscopy, 244 (2), 113-116.
https://corescholar.libraries.wright.edu/physics/770

DOI

10.1016/j.jms.2007.06.002