Publication Date

2024

Document Type

Thesis

Committee Members

H. Daniel Young, Ph.D. (Advisor); Hong Huang, Ph.D. (Committee Member); Randall Hay, Ph.D. (Committee Member)

Degree Name

Master of Science in Materials Science and Engineering (MSMSE)

Abstract

Zinc sulfide has an infrared cutoff in the LWIR, but its low hardness makes it susceptible to rain erosion and abrasion. A composite of cerium oxide and zinc sulfide that retains an infrared cutoff in the LWIR, and with hardness higher than pure zinc sulfide is a potential solution to the rain erosion and abrasion issue. Several different processes were undertaken in this project to produce such a composite. The different reactions between ZnS and CeO2 were researched, along with the effects of different processing parameters. Composite samples were made that had a better hardness than zinc sulfide but did not reach a significant level of LWIR transparency, except for one composition, Ce2O4 5La2O3 ZnS 10-90. This composite showed a significant issue with oxidation at high temperatures.

Page Count

92

Department or Program

Department of Mechanical and Materials Engineering

Year Degree Awarded

2024


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