Publication Date

2024

Document Type

Thesis

Committee Members

Steven R. Higgins, Ph.D. (Advisor); Lindsay Starr, Ph.D. (Committee Member); Chia-Yu Wu, Ph.D. (Committee Member)

Degree Name

Master of Science (MS)

Abstract

This study investigates the distribution of water pollutants in the urban and suburban watershed (Beavercreek Sub-watershed (BCS) and Little Beavercreek Sub-watershed (LBS)) of Dayton, Ohio USA focusing on the relationship between water quality and land use types based on 2021 land use maps obtained from MRLC. These watersheds are home for aquatic life and regulate the flow of surface water and recharge groundwater so, it is crucial to maintain good water quality by balancing urbanization and farmland within these two watersheds. We analyzed chloride, nitrate, and sulfate using ion chromatography (IC) and orthophosphate using UV/Vis Spectrophotometry. Additionally, three pesticides (Atrazine, Diazinon, and Dichlorophenoxyacetic acid (2,4-D)) were selected and identified by analytical methodology using solid-phase extraction (SPE) followed by liquid chromatography with mass spectrometry (LC-MS) temporally. The chloride is dominant in both watersheds followed by sulfate, nitrate, and orthophosphate. 2,4-D was most common with higher concentrations in BCS (51%) than in LBS (35%). The impact of agricultural runoff on water quality is seen in the streams of LBS which correspond to higher levels of nitrate, sulfate, and orthophosphate. There were significant differences between BCS and LBS for 2,4-D (p-value 0.03 <0.05) and atrazine, diazinon showed no significant differences (p-value > 0.05 in both watersheds.

Page Count

123

Department or Program

Department of Earth and Environmental Sciences

Year Degree Awarded

2024

ORCID ID

0009-0004-4070-9388


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