G. Allen Burton (Committee Chair), Songlin Cheng (Committee Member), David Dominic (Committee Member), Chad Hammerschmidt (Committee Member)
Master of Science (MS)
Using batch and stream recirculating flume experiments to compare and contrast one clayey sediment (Warden Ditch) and two analytical grade clay minerals (montmorillonite and kaolinite), the dynamic interactions between two aquatic stressors (suspended solids and nickel) were explored. Aldrich humic acid was incorporated to demonstrate the mitigating effects of dissolved organic carbon (DOC) on Ni toxicity. The flux of Ni between compartments (dissolved and sorbed) was quantified as a partition/distribution coefficient. The USEPA test organism Daphnia magna (neonates, < 24 h) was utilized to evaluate toxicity in dynamic non-renewal, short-term bioassays. Generally, toxicity showed a linear relationship with turbidity level. Conversely, sorption coefficients were experiment specific, making them difficult to predict and assess. Clay functioned as an adsorbent, scavenging Ni. Results support the hypotheses that solids and metals act as stressors in streams, DOC attenuates the toxicity of Ni, and Ni fluxes quickly between system compartments.
Department or Program
Department of Earth and Environmental Sciences
Year Degree Awarded
Copyright 2008, all rights reserved. This open access ETD is published by Wright State University and OhioLINK.