Experimental and Theoretical Study of Strong Low-Terahertz Absorption of Thymine
The absorption coefficient of a nucleobase-thymine-in powder form was measured with terahertz spectroscopy in both frequency- and time-domain experiments. For frequencies below 3 THz, a strong signature was observed at 1.27 THz. Furthermore, molecular-dynamic simulations were conducted to reveal that the 1.27 THz absorption signature is related to a transverse optical phonon mode. The simulations also indicated that bound water molecules are vital to the vibrational mode.
Zhang, W. D.,
Deibel, J. A.,
& Brown, E. R.
(2017). Experimental and Theoretical Study of Strong Low-Terahertz Absorption of Thymine. Journal of Infrared, Millimeter, and Terahertz Waves, 38, 1521-1529.