Millimeter and Submillimeter-Wave Spectrum of Hydrogen Peroxide in the Ground and v₃=1 Vibrational States

Authors

Douglas T. Petkie, Wright State University - Main CampusFollow
Thomas M. Goyette
Frank C. De Lucia
Paul Helminger
S. P. Belov
G. Winnewisser

Document Type

Article

Publication Date

11-1998

Abstract

The first measurements of the millimeter- and submillimeter (mm/submm)-wave rotational–torsional transitions in the v₃= 1 ground torsional state (n= 0) of hydrogen peroxide are reported. The 149 newly measured transitions extend from 72 to 623 GHz in frequency and up to J= 32 and K_a= 3 in rotational quantum number. Additional measurements in the ground vibrational and torsional state around 1 THz are also reported. These data, along with all previously published microwave, mm/submm-wave, and far infrared data in the ground and v₃= 1 vibrational state, along with recent infrared measurements, have been fitted simultaneously to their respective experimental uncertainties using a multi-state Hamiltonian that includes Fermi- and Coriolis-type interactions.

Repository Citation

Petkie, D. T., Goyette, T. M., De Lucia, F. C., Helminger, P., Belov, S. P., & Winnewisser, G. (1998). Millimeter and Submillimeter-Wave Spectrum of Hydrogen Peroxide in the Ground and v₃=1 Vibrational States. Journal of Molecular Spectroscopy, 192 (1), 25-31.
https://corescholar.libraries.wright.edu/physics/784

DOI

10.1006/jmsp.1998.7651