Thermodynamics of Binary Solutions of Nonelectrolytes with 2,2,4-Trimethylpentane. II. Phase Equilibrium Study with Cyclohexane and a New Cooling Curve Apparatus
Document Type
Article
Publication Date
11-1966
Abstract
The phase equilibrium of the cyclohexane2,2,4-trimethylpentane system was established over the entire range of composition by cooling curve analysis. There is a eutectic at -113.95 degrees and a mole fraction of cyclohexane of 0.25. The phase transition for cyclohexane (solid I to 11) is at -87.06 degrees and the break in the solubility curve comes at a mole fraction of cyclohexane of 0.65. The calculated ideal solubility of cyclohexane is close to the experimental solubility, confirming the nearly ideal behavior that this system exhibited in other studies. A new cooling curve apparatus is described.
Repository Citation
Battino, R.,
& Allison, G. W.
(1966). Thermodynamics of Binary Solutions of Nonelectrolytes with 2,2,4-Trimethylpentane. II. Phase Equilibrium Study with Cyclohexane and a New Cooling Curve Apparatus. The Journal of Physical Chemistry, 70 (11), 3417-3419.
https://corescholar.libraries.wright.edu/chemistry/115
DOI
10.1021/j100883a008
