Publication Date
2018
Document Type
Thesis
Committee Members
Hong Huang (Advisor), Maher Amer (Committee Member), Suzanne Lunsford (Committee Member)
Degree Name
Master of Science in Materials Science and Engineering (MSMSE)
Abstract
Solar technology has a long history of incremental improvements in cost, reliability and efficiency. However, solar cells based on lead halide perovskite films have made more rapid leaps forward in the past 10 years, making it the fastest growing solar technology in terms of efficiency. Leaders in academia and industry continue to find success in overcoming manufacturability and stability issues, but have not yet discovered a high-efficiency perovskite film without the use of toxic lead. Probing less toxic analogs to the highly efficient lead halide, a series of thin films with perovskite structures, i.e. A2BB’X6 where A = Cs or FA, B/B’ = Sn, Bi, Sb, Ag, and/or In and X = I, are fabricated using a mixed metal approach. XRD patterns reveal the low dimensional A3Bi2I9 crystal. UV/Vis spectra results show that the bandgap of bismuth-based perovskites is finely tuned, which has potential applications in future solar cells.
Page Count
94
Department or Program
Department of Mechanical and Materials Engineering
Year Degree Awarded
2018
Copyright
Copyright 2018, some rights reserved. My ETD may be copied and distributed only for non-commercial purposes and may not be modified. All use must give me credit as the original author.
Creative Commons License
This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 3.0 License.
ORCID ID
0000-0001-7566-5611